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Room temperature rate coefficient for the reaction between CH3O2 and NO3

✍ Scribed by J. N. Crowley; J. P. Burrows; G. K. Moortgat; G. Poulet; G. LeBras

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 507 KB
Volume: 22
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550220703

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✦ Synopsis

The molecular modulation spectroscopic technique was employed to study the kinetics of NO3 radicals produced in the 253.7 nm photolysis of flowing gas mixtures of HNO3/CH4/O2 at room temperature. By computer fitting of the NO, temporal behavior, a rate coefficient of (2.3 ? 0.7) x lo-'' cm3 molecule-' s-l was obtained for the reaction between NO3 and CH302 at 298 K.

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