𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Investigation of the rate coefficient for O(3p) + NO2 → O2 + NO

✍ Scribed by Tom G. Slanger; Bernard J. Wood; Graham Black

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
264 KB
Volume
5
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Measurements of the rate coefficient of the reaction (O^3^P) + NO~2~ → O~2~ + NO have been made at 296°K and 240°K, using the technique of NO~2~* chemiluminescent decay. Values of 9.3 × 10^−12^ cm^3^ molec^−1^ sec^−1^ at 296°K and 10.5 × 10^−12^ cm^3^ molec^−1^ sec^−1^ at 240°K were obtained, in excellent agreement with the recent results of Davis, Herron, and Huie [1]. The earlier lower values may have resulted from loss of NO~2~ on surfaces.

📜 SIMILAR VOLUMES

The rate constant of NO + O3 → NO2 + O2
The rate constant of NO + O3 → NO2 + O2 in the temperature range of 283–443 K
✍ H. H. Lippmann; Barbara Jesser; Ulrich Schurath 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 398 KB

## Abstract The reaction NO + O~3~ → NO~2~ + O~2~ has been studied in a 220‐m^3^ spherical stainless steel reactor under stopped‐flow conditions below 0.1 mtorr total pressure. Under the conditions used, the mixing time of the reactants was negligible compared with the chemical reaction time. The p

Rate coefficients for the gas-phase reac
Rate coefficients for the gas-phase reaction of isoprene with NO3 and NO2
✍ Jeanette R. Stabel; Matthew S. Johnson; Sarka Langer 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 207 KB 👁 2 views

## Abstract Rate coefficients for the gas‐phase reaction of isoprene with nitrate radicals and with nitrogen dioxide were determined. A Teflon collapsible chamber with solid phase micro extraction (SPME) for sampling and gas chromatography with flame ionization detection (GC/FID) and a glass reacto

The NO Vibrational Fundamental Band: O2-
The NO Vibrational Fundamental Band: O2-Broadening Coefficients
✍ C. Chackerian Jr.; R.S. Freedman; L.P. Giver; L.R. Brown 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 144 KB

The first measurements of O 2 broadening of NO lines is reported. For the NO fundamental vibration-rotation band, polynomial representations for this broadening at 299 K are given for ⍀ ϭ 3 2 and ⍀ ϭ 1 2 e and f transitions, respectively: f ͑|m|͒ ϭ 0.06515 Ϫ 0.00381|m| ϩ 0.000271|m| 2 Ϫ 0.00000665

Evaluating data for atmospheric models,
Evaluating data for atmospheric models, an example: CH3O2 + NO2 = CH3O2NO2
✍ David M. Golden 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 279 KB

## Abstract Data in both directions for the title reaction have been statistically fit (weighted nonlinear least squares) to the different formalisms used by the NASA and IUPAC data evaluation panels. The data are well represented by either formalism. Master equation/RRKM methods were then employed

Ab initio study of the mechanism of the
Ab initio study of the mechanism of the atmospheric reaction: NO2 + O3 → NO3 + O2
✍ Julio Peiró-García; Ignacio Nebot-Gil 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 146 KB 👁 1 views

## Abstract The atmospheric reaction NO~2~ + O~3~ → NO~3~ + O~2~ (1) has been investigated theoretically by using the MP2, G2, G2Q, QCISD, QCISD(T), CCSD(T), CASSCF, and CASPT2 methods with various basis sets. The results show that the reaction pathway can be divided in two different parts at the M

Atmospheric chemistry of acetone: Kineti
Atmospheric chemistry of acetone: Kinetic study of the CH3C(O)CH2O2+NO/NO2 reactions and decomposition of CH3C(O)CH2O2NO2
✍ Jens Sehested; Lene K. Christensen; Ole J. Nielsen; Merete Bilde; Timothy J. Wal 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 290 KB 👁 2 views

Pulse radiolysis was used to study the kinetics of the reactions of CH 3 C(O)CH 2 O 2 radicals with NO and NO 2 at By monitoring the rate of formation and decay of NO 2 295 K. using its absorption at the rate constants 400 and 450 nm k(CH C(O)CH O ϩ NO) ϭ (8 Ϯ 3 2 2 and were de-Ϫ12 Ϫ12 3 Ϫ1 Ϫ1 2) ϫ