✦ LIBER ✦

Rate coefficient for the reaction between NO3 radicals and dimethyl sulphide

✍ Scribed by G.S. Tyndall; J.P. Burrows; W. Schneider; G.K. Moortgat

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 304 KB
Volume: 130
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80506-1

No coin nor oath required. For personal study only.

✦ Synopsis

The rate coeffkient for reaction between NOz and dimethyl sulphide has been measured to be ( 1 .O + 0.2) x 10 -I2 cm -3 molecule-' s-' independent of temperature between 278 and 318 K. No evidence was found for a reaction channel producing NO2 and dimethyl sulphoxide.

📜 SIMILAR VOLUMES

Room temperature rate coefficient for th

Room temperature rate coefficient for the reaction between CH3O2 and NO3

✍ J. N. Crowley; J. P. Burrows; G. K. Moortgat; G. Poulet; G. LeBras 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 507 KB

The molecular modulation spectroscopic technique was employed to study the kinetics of NO3 radicals produced in the 253.7 nm photolysis of flowing gas mixtures of HNO3/CH4/O2 at room temperature. By computer fitting of the NO, temporal behavior, a rate coefficient of (2.3 ? 0.7) x lo-'' cm3 molecule

Rate coefficient for the reaction of CCl

Rate coefficient for the reaction of CCl3 radicals with ozone

✍ Takashi Imamura; Hideharu Chono; Kazuhiko Shibuya; Nobuaki Washida 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 108 KB 👁 1 views

## Abstract The rate coefficient for the reaction of CCl~3~ radicals with ozone has been measured at 303 ± 2 K. The CCl~3~ radicals were generated by the pulsed laser photolysis of carbon tetrachloride at 193 nm. The time profile of CCl~3~ concentration was monitored with a photoionization mass spe

Rate coefficients for the gas-phase reac

Rate coefficients for the gas-phase reaction of NO3 radicals with selected dihydroxybenzenes

✍ R. I. Olariu; I. Bejan; I. Barnes; B. Klotz; K. H. Becker; K. Wirtz 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 121 KB 👁 1 views

## Abstract Using a relative kinetic technique, rate coefficients have been determined at (298 ± 2) K and atmospheric pressure for the gas‐phase reactions of the NO~3~ radical with three vicinal dihydroxy aromatic compounds. The experiments were carried out in a 1080‐l quartz glass reactor at the B

Rate coefficients for the gas-phase reac

Rate coefficients for the gas-phase reaction of isoprene with NO3 and NO2

✍ Jeanette R. Stabel; Matthew S. Johnson; Sarka Langer 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 207 KB 👁 2 views

## Abstract Rate coefficients for the gas‐phase reaction of isoprene with nitrate radicals and with nitrogen dioxide were determined. A Teflon collapsible chamber with solid phase micro extraction (SPME) for sampling and gas chromatography with flame ionization detection (GC/FID) and a glass reacto

Rate constant for the reaction of OH rad

Rate constant for the reaction of OH radicals with dimethyl sulfide

✍ Yen-Chung Hsu; Dze-Shu Chen; Yuan-Pern Lee 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 485 KB 👁 2 views

The rate constants of the gas phase reaction of OH radicals with dimethyl sulfide (CH3SCH3) over the temperature range 260-393 K have been studied using the discharge flow-resonance fluorescence technique. The rate constants were fitted by the Arrhenius equation k = (11.8 2 2.2) x exp[-(236 2 150)/T

Gas-phase rate constants for the reactio

Gas-phase rate constants for the reaction of NO3 radicals with selected oxiranes

✍ I. Kind; T. Berndt; O. Böge; W. Rolle 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 268 KB

The gas-phase reaction of NO 3 radicals with selected oxiranes has been studied in a flow system at T = 295 + 2 K in the pressure range 3.4-50 mbar using N 2 as carrier gas. The analysis of the organics was performed by means of on-line connected GC-FID. Rate constants were obtained with the relativ