✦ LIBER ✦

Rate coefficients for CS reactions with O2, O3 and NO2 AT 298 K

✍ Scribed by G. Black; L.E. Jusinski; T.G. Slanger

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 383 KB
Volume: 102
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80659-9

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✦ Synopsis

CS radicals have been produced by photodissociation of CS2 at 193 MI and their disappearance monitored by LIF_ The vibrationally excited CS radicals rapidly relax to CS(v = 0). At 298 K, the rate coeffkients for CS(u = 0) reactions with 02, 03 and NO* are (2.9 +_ 0.4) x lo-", (3.0 + 0.4) X lo-I6 and (7.6 f 1.1)~ 10-I' an3 molecule-' i' respectively. The quenching of CS(A *II)v.=~ by He has a rate coefficient of (1.3 * 0.2) x IO-'* cm3 molecule-' s-r_

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