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Collisional quenching rate coefficients for the reaction of N2+* + N2, NO+* + NO and O2+* + O2 AT 300 K

โœ Scribed by A.B. Rakshit


Publisher
Elsevier Science
Year
1980
Weight
416 KB
Volume
36
Category
Article
ISSN
0020-7381

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Rcccivcd 30 Apnl 1982 SO:, photodissociation at 193 nm (AIF cxclmer lmr) ha been used to create SO radicals; the chcmdumincsccncc from the SO + 03 reaction has been used to follow the SO ndical decay. Rate coefticicnls at 298 K of (1 07 t 0.16) x 10-r6, (1 06 f 0 16) x 10-r3, and (1 48 k 0 20) x IO-

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Flash photolysis of NO coupled with time resolved detection of 0 via resonance fluorescence has been used to obtain rate constants for the reaction 0 + NO f N2 --, NO2 + Na ar temperatures from 217 to 500 K. The measured rate constxrts obey the Arrhenius equation k = (is.5 + 2.0) X 1O-33 -2 exp[(ll6

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The reactions of labeled NL5NOwith CO, NO, 02, "02, N,, NO2, and N,O have been investigated using a tandem ICR instrument. In each case the total rate coefficient, product distribution, and kinetic energy dependence were measured. The results indicate that very specific reaction mechanisms govern th

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## Abstract Measurements of the rate coefficient of the reaction (O^3^__P__) + NO~2~ โ†’ O~2~ + NO have been made at 296ยฐK and 240ยฐK, using the technique of NO~2~\* chemiluminescent decay. Values of 9.3 ร— 10^โˆ’12^ cm^3^ molec^โˆ’1^ sec^โˆ’1^ at 296ยฐK and 10.5 ร— 10^โˆ’12^ cm^3^ molec^โˆ’1^ sec^โˆ’1^ at 240ยฐK wer