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Rate coefficients at 298 K for SO reactions with O2, O3, and NO2

โœ Scribed by G. Black; R.L. Sharpless; T.G. Slanger

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
271 KB
Volume
90
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Rcccivcd 30 Apnl 1982 SO:, photodissociation at 193 nm (AIF cxclmer lmr) ha been used to create SO radicals; the chcmdumincsccncc from the SO + 03 reaction has been used to follow the SO ndical decay. Rate coefticicnls at 298 K of (1 07 t 0.16) x 10-r6, (1 06 f 0 16) x 10-r3, and (1 48 k 0 20) x IO-" cm3 molecule-' s-l were measured for the ractions of SO with 02, 03, and NOz, respectively.

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Rate coefficients for CS reactions with
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CS radicals have been produced by photodissociation of CS2 at 193 MI and their disappearance monitored by LIF\_ The vibrationally excited CS radicals rapidly relax to CS(v = 0). At 298 K, the rate coeffkients for CS(u = 0) reactions with 02, 03 and NO\* are (2.9 +\_ 0.4) x lo-", (3.0 + 0.4) X lo-I6

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