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The mechanism of SO2 oxidation by CH3O2 radicals. Rate coefficients for the reactions of CH3O2 with SO2 and NO

✍ Scribed by R. Simonaitis; J. Heicklen

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 237 KB
Volume: 65
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)87082-7

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✦ Synopsis

The reacttonsof CH30z nitIt SO2 and NO haw been studied bv steady state photo&s of azomethane in the presence of Ot-SOz-SO mixtures at 196 M and I ;Ltm total pressure. Thr quantum yield of NO otidntion by CHxO= m.dicxG is increased substanthlIy when SO? is added ro the system indicating an SOa induced chain oxidation of X0. The rare isw gbes -CH30 t KOz (1). Combining this ratio with the absolute value ofkr = 8.2 X IO-" cm3 se1 gibes X-2 = 10

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