✦ LIBER ✦

The reaction of CH3O2 radicals with NO2

✍ Scribed by Hiroyuki Adachi; Norman Basco

Publisher: John Wiley and Sons
Year: 1980
Tongue: English
Weight: 881 KB
Volume: 12
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550120102

No coin nor oath required. For personal study only.

✦ Synopsis

The rate constant for the reaction CH302 + NO2 -(products) has been measured directly by flash photolysis and kinetic spectroscopy. At room temperature and a t total pressures between 53 and 580 Torr, k:, = (9.2 f 0.4) X lo8 liter/mole sec so that the rate of formation of the probable primary product peroxymethyl nitrate (CH302N02) may be significant in urban atmospheres.

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