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Rate constants for the gas-phase reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2

✍ Scribed by Ole J. Nielsen; Howard W. Sidebottom; Denis J. O'Farrell; Michael Donlon; Jack Treacy

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 514 KB
Volume: 156
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(89)87099-x

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✦ Synopsis

Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy and a conventional photolytic relative rate method. The Cl rate constants were measured using only the relative rate method. The results are discussed in terms of reactivity trends.

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