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Excess molar volumes of {x1CH3CH2COOCH2CH3+x2CH3(CH2)4CH3+ (1 −x1−x2)CH3(CH2)2OH or CH3(CH2)3OH} at the temperature 298.15 K

✍ Scribed by E. Jiménez; C. Franjo; C.P. Menaut; L. Segade; J.L. Legido; M.I. Paz Andrade

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
265 KB
Volume
29
Category
Article
ISSN
0021-9614

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✦ Synopsis

Excess molar volumes at the temperature 298.15 K were measured for

, and {xCH3(CH2)4 CH3 +(1x)CH3(CH2)3OH}. Excess molar volumes were determined using an Anton Paar DMA 60/602 densimeter. The experimental values obtained in this work were compared with results obtained using methods which estimate ternary properties from binary results.

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Excess molar volumes V E m of the ternary mixture {x1CH3(CH2)3OH+x2CH3(CH2)4CH3 + (1-x1-x2)CH3(CH2)3NH2} at the temperatures 298.15 K and 313.15 K, and the binary mixtures {xCH3(CH2)3OH + (1-x)CH3(CH2)3NH2}, {xCH3(CH2)4CH3 + (1-x)CH3(CH2)3NH2} at T=313.15 K have been determined from density measurem

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Excess molar volumes at the temperature \(298.15 \mathrm{~K}\) of \(\left[x_{1} \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CO}_{2}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{CH}_{3}+\right.\) \(x_{2} \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{5} \mathrm{OH}+\left(1-x_{1}-x_{2}\right)\left\{\mathrm{CH}_{

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## Excess molar volumes at CH2 )n-2CH3}, (n= 10 or n = 12), and {xCH3(CH2)3CH2Cl + (1x)CH3(CH2)n-2CH3}, (n= 10 or n = 12), were determined using a densimeter Anton Paar DMA 60/602. All the experimental values were compared with the results obtained by empirical expressions for estimating ternar

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Vigo, Espana ˜Ä Ž Density and refractive index data in the binary mixtures xCH COOCH q 1 y 3 3 . Ž . Ž .4 Ä Ž . Ž . Ž .4 xCH CH C OH CH and xCH OH q 1 y x CH CH C OH CH , and the ternary 3 2 3 2 3 3 2 3 2 sented at T s 298.15 K over the whole range of mole fractions and atmospheric pressure. These

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Densities, refractive indices, and derived excess properties of {x1CH3COOCH3+x2CH3OH+(1−x1−x2)CH3CH(OH)CH3} at the temperature 298.15 K
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## Densities and refractive indices of {x1CH3COOCH3 , and {xCH3OH + (1 -x)CH3CH(OH)CH3} have been determined experimentally as a function of the mole fraction(s) at the temperature 298.15 K and atmospheric pressure. A vibrating tube digital densimeter and an Abbe-type refractometer of synthetic s