✦ LIBER ✦

Rate studies of the reactions of the (CH3)2N radical with O2, NO, and NO2

✍ Scribed by Charlet R.C. Lindley; Jack G. Calvert; John H. Shaw

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 527 KB
Volume: 67
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)87105-5

No coin nor oath required. For personal study only.

✦ Synopsis

The hinetics of the reactions of the (CI13)2K rrtduxl wthX0.N02,and O2 rrere studied usins FTIR spectroscopy. The tutwe of the products and the ratio ofr.~tc constants for these reactions acre dctermmed_ The results were used to evalu.rte the potenti.n for nitros.unine .md nitramine formation in X0-X0,-hydrocarbon-amine-polluted atmospheres.

📜 SIMILAR VOLUMES

The reaction of CH3O2 radicals with NO2

✍ Hiroyuki Adachi; Norman Basco 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 881 KB

The rate constant for the reaction CH302 + NO2 -(products) has been measured directly by flash photolysis and kinetic spectroscopy. At room temperature and a t total pressures between 53 and 580 Torr, k:, = (9.2 f 0.4) X lo8 liter/mole sec so that the rate of formation of the probable primary produc

Rate constants for the gas-phase reactio

Rate constants for the gas-phase reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2

✍ Ole J. Nielsen; Howard W. Sidebottom; Denis J. O'Farrell; Michael Donlon; Jack T 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 514 KB

Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co

Atmospheric chemistry of acetone: Kineti

Atmospheric chemistry of acetone: Kinetic study of the CH3C(O)CH2O2+NO/NO2 reactions and decomposition of CH3C(O)CH2O2NO2

✍ Jens Sehested; Lene K. Christensen; Ole J. Nielsen; Merete Bilde; Timothy J. Wal 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 290 KB 👁 2 views

Pulse radiolysis was used to study the kinetics of the reactions of CH 3 C(O)CH 2 O 2 radicals with NO and NO 2 at By monitoring the rate of formation and decay of NO 2 295 K. using its absorption at the rate constants 400 and 450 nm k(CH C(O)CH O ϩ NO) ϭ (8 Ϯ 3 2 2 and were de-Ϫ12 Ϫ12 3 Ϫ1 Ϫ1 2) ϫ

The mechanism of SO2 oxidation by CH3O2

The mechanism of SO2 oxidation by CH3O2 radicals. Rate coefficients for the reactions of CH3O2 with SO2 and NO

✍ R. Simonaitis; J. Heicklen 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 237 KB

The reacttonsof CH30z nitIt SO2 and NO haw been studied bv steady state photo&s of azomethane in the presence of Ot-SOz-SO mixtures at 196 M and I ;Ltm total pressure. Thr quantum yield of NO otidntion by CHxO= m.dicxG is increased substanthlIy when SO? is added ro the system indicating an SOa induc

Rate constant for the reaction of CH3O2

Rate constant for the reaction of CH3O2 with NO

✍ Akira Masaki; Shigeru Tsunashima; Nobuaki Washida 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 493 KB

The CHsOs radical was generated by pulsed laser photolysis and was detected directly by photoionization mass spectrometry. The radical was photoionized by the Ar resonance lines ( 11.62 and 11.83 eV) and detected as the parent ion, CHsO: . Reactions of CH302 and CDs02 with NO were studied by time-re

Temperature dependence of the reaction o

Temperature dependence of the reaction of NO with CFCl2CH2O2 and CH3CFClO2 radicals

✍ Fuxiang Wu; Robert W. Carr 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 729 KB

The reaction of NO with the peroxy radical CFC12CH202, and with CH3CFClO2 was investigated at 8-20 torr and 263-321 K by UV flash photolysis of CFCI2CH3/O2/NO gas mixtures The kinetics were determined from observations of the growth rate of the CFC12CH20 radical and the decay rate of NO by time-reso