✦ LIBER ✦

Rate constant for the reaction of CH3O2 with NO

✍ Scribed by Akira Masaki; Shigeru Tsunashima; Nobuaki Washida

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 493 KB
Volume: 218
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00024-7

No coin nor oath required. For personal study only.

✦ Synopsis

The CHsOs radical was generated by pulsed laser photolysis and was detected directly by photoionization mass spectrometry. The radical was photoionized by the Ar resonance lines ( 11.62 and 11.83 eV) and detected as the parent ion, CHsO: . Reactions of CH302 and CDs02 with NO were studied by time-resolved measurements of the radical ion signals. The following rate constants were obtained at 298fS K: k(CHs02+NO)=(11.2f 1.4)x 10-t* cm' molecule-' s-' and k(CD302+NO)= ( 10.9 f 1.3) x 10-t* cm3 molecule-' s-'. The values are 50% larger than those previously reported.

📜 SIMILAR VOLUMES

Absolute rate constant for the reaction

Absolute rate constant for the reaction of CH with O2

✍ I. Messing; C.M. Sadowski; S.V. Filseth 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 441 KB

## CH(X"iI ) h;cs been produced in the muItipIe-photon dissociation ofmethykunine by a TEA CO2 I~.ser-Laser-induced fluorescence has been used to measure relative CH concentrations zz a function of time and added gs pressures-ChemiIuminescence which accompanies the reaction is due to the productio

Absolute rate constant for the CH + O re

Absolute rate constant for the CH + O reaction

✍ I. Messing; T. Carrington; S.V. Filseth; C.M. Sadowski 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 148 KB

Recelvcd 28 Apnl 1980. m final form 2 June 1980 CH (>(' fl) was produced by multiple mfrared photon dlssoclatlon of CH30H kapour m the presence of excess atomic oxygen Tune-resolved measurements of relative CH concentrations were made at 298 K \\xth a tunable dye laser. From the dependence of CH dec

Rate constants for reactions of CH3O2 in

Rate constants for reactions of CH3O2 in the gas phase

✍ R.A. Cox; G.S. Tyndall 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 189 KB

## Receiwd 16 Ma> 1979 MoIecuhr modulation spectrometry has been employed to mesure the rate constants for the reactions ofCHxO2 with HOz. NO2 and X0. A negnthe tcmpcraturc dependence is reported for the rextion nirh HO\_r. Product spectra are giwn for the reactions with lIOt and NO?\_

Rate constant for the reaction of CH3C(O

Rate constant for the reaction of CH3C(O)CH2 radical with HBr and its thermochemical implication

✍ Edit Farkas; Gergely Kovács; István Szilágyi; Sándor Dóbé; Tibor Bérces; Ferenc 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 102 KB 👁 1 views

## Abstract The fast flow method with laser induced fluorescence detection of CH~3~C(O)CH~2~ was employed to obtain the rate constant of __k__~1~ (298 K) = (1.83 ± 0.12 (1σ)) × 10^10^ cm^3^ mol^−1^ s^−1^ for the reaction CH~3~C(O)CH~2~ + HBr ↔ CH~3~C(O)CH~3~ + Br (1, −1). The observed reduced react

Rate constants for the gas-phase reactio

Rate constants for the gas-phase reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2

✍ Ole J. Nielsen; Howard W. Sidebottom; Denis J. O'Farrell; Michael Donlon; Jack T 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 514 KB

Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co

The rate constant for the reaction O3 +

The rate constant for the reaction O3 + NO2 → O2 + NO3 over the temperature range 259–362 °K

✍ Robert E. Huie; John T. Herron 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 299 KB