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Absolute rate constant for the reaction of CH with O2

✍ Scribed by I. Messing; C.M. Sadowski; S.V. Filseth

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 441 KB
Volume: 66
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)80375-9

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✦ Synopsis

CH(X"iI

) h;cs been produced in the muItipIe-photon dissociation ofmethykunine by a TEA CO2 I~.ser-Laser-induced fluorescence has been used to measure relative CH concentrations zz a function of time and added gs pressures-ChemiIuminescence which accompanies the reaction is due to the production of OH(A ZZt) in the reaction_ The rrrte constant obtained from the fluorescence experiments is (3.; t 0.4) X IO-t1 cm3 moIecuIe_t s-l at 298 I(, in agreement with that deduced from

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