✦ LIBER ✦

The reactions of isotopically labeled N15NO+ with CO, NO, O2, N2, NO2, and N2O

✍ Scribed by Paul R. Kemper; M. T. Bowers

Publisher: John Wiley and Sons
Year: 1984
Tongue: English
Weight: 893 KB
Volume: 16
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550160608

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✦ Synopsis

The reactions of labeled NL5NOwith CO, NO, 02, "02, N,, NO2, and N,O have been investigated using a tandem ICR instrument. In each case the total rate coefficient, product distribution, and kinetic energy dependence were measured. The results indicate that very specific reaction mechanisms govern these reactions. This conclusion is suggested by the lack of isotopic scrambling in many cases and by the complete absence of energetically allowed products in almost all of the systems. The kinetic energy studies indicate that most of the reaction channels proceed through an intermediate complex at low energies and via a direct mechanism at higher kinetic energies. Such direct mechanisms include long range charge transfer and atom or ion transfer.

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