Poly[[(2-iodopyrazine-κN4)copper(I)]-μ3-thiocyanato-κ3N:S:S]
✍ Scribed by Näther, Christian ;Wriedt, Mario ;Jeß, Inke
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 581 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the crystal structure of the title compound, [Cu(NCS)-(C 4 H 3 IN 2 )] n , each Cu atom is coordinated by three thiocyanate anions and one 2-iodopyrazine ligand within a distorted tetrahedron. The Cu-coordinated units form dimers, which are connected into layers by the thiocyanate anions.
📜 SIMILAR VOLUMES
The title compound, [Cu(SCN)(C~3~H~5~NS~2~)]~__n__~, was prepared from the direct reaction between copper(I) thiocyanate and 1,3-thiazolidine-2-thione. The structure is an infinite two-dimensional polymer, parallel to the __ac__ plane, with tetrahedrally distorted Cu atoms which are coordinated by t
The NCS ligand in the title compound, [Cu(NCS)(C 10 H 9 N 3 )] n , bridges adjacent tetrahedral Cu I atoms through the sulfur end into a linear chain that runs along the b axis of the orthorhombic unit cell.
The isothiocyanate ligand in the title compound, [Cu(NCS)(C~18~H~12~N~2~)]~__n__~, links adjacent tetrahedral Cu^I^ atoms into a zigzag chain; the Cu lies on a mirror plane that bisects the chelating biquinoline ligand.
The title compound, [Cd("-SCN) 2 (C 7 H 7 NO 2 ) 2 ] n , has been prepared from the reaction of 3-aminobenzoic acid, NH 4 SCN and Cd(NO 3 ) 2 Á6H 2 O in MeOH/H 2 O. It consists of onedimensional polymeric chains, which are extended into a two-dimensional layer structure by head-to-head hydrogen bond