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catena-Poly[[(di-2-pyridylamine-κ2N,N′)copper(I)]-μ-isothio­cyanato-κ2S:S]

✍ Scribed by Zhou, Rui ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
184 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The NCS ligand in the title compound, [Cu(NCS)(C 10 H 9 N 3 )] n , bridges adjacent tetrahedral Cu I atoms through the sulfur end into a linear chain that runs along the b axis of the orthorhombic unit cell.

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✍ Zhou, Rui ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 163 KB

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In the title compound, [Co(NCS)~2~(C~10~H~9~N~3~)], a Co^II^ atom with tetrahedral coordination is bound by two __N__-donor thiocyanate anions and two __N__-donor atoms from two crystallographically distinct di-4-pyridylamine (dpa) ligands whose central NH units lie on twofold axes. The dpa ligands

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✍ Saithong, Saowanit ;Pakawatchai, Chaveng ;Charmant, Jonathan P. H. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 188 KB

The title compound, [Cu(SCN)(C~3~H~5~NS~2~)]~__n__~, was prepared from the direct reaction between copper(I) thiocyanate and 1,3-thiazolidine-2-thione. The structure is an infinite two-dimensional polymer, parallel to the __ac__ plane, with tetrahedrally distorted Cu atoms which are coordinated by t