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Poly[μ-1,3-thia­zolidine-2-thione-κ2S2:S2-μ-thio­cyanato-κ2S:N-copper(I)]

✍ Scribed by Saithong, Saowanit ;Pakawatchai, Chaveng ;Charmant, Jonathan P. H.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
188 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Cu(SCN)(C~3~H~5~NS~2~)]~n~, was prepared from the direct reaction between copper(I) thiocyanate and 1,3-thiazolidine-2-thione. The structure is an infinite two-dimensional polymer, parallel to the ac plane, with tetrahedrally distorted Cu atoms which are coordinated by the S and N atoms of the thiocyanate ions, and by the thione S atom of 1,3-thiazolidine-2-thione molecules.

📜 SIMILAR VOLUMES

Poly­[[(2-iodo­pyrazine-κN4)copper(I)]-μ
Poly­[[(2-iodo­pyrazine-κN4)copper(I)]-μ3-thio­cyanato-κ3N:S:S]
✍ Näther, Christian ;Wriedt, Mario ;Jeß, Inke 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 581 KB

In the crystal structure of the title compound, [Cu(NCS)-(C 4 H 3 IN 2 )] n , each Cu atom is coordinated by three thiocyanate anions and one 2-iodopyrazine ligand within a distorted tetrahedron. The Cu-coordinated units form dimers, which are connected into layers by the thiocyanate anions.

catena-Poly[[(di-2-pyridylamine-κ2N,N′)c
catena-Poly[[(di-2-pyridylamine-κ2N,N′)copper(I)]-μ-isothio­cyanato-κ2S:S]
✍ Zhou, Rui ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 184 KB

The NCS ligand in the title compound, [Cu(NCS)(C 10 H 9 N 3 )] n , bridges adjacent tetrahedral Cu I atoms through the sulfur end into a linear chain that runs along the b axis of the orthorhombic unit cell.

catena-Poly[[(2,2′-biquinoline-κ2N,N′)co
catena-Poly[[(2,2′-biquinoline-κ2N,N′)copper(I)]-μ-isothio­cyanato-κ2N:S]
✍ Zhou, Rui ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 163 KB

The isothiocyanate ligand in the title compound, [Cu(NCS)(C~18~H~12~N~2~)]~__n__~, links adjacent tetrahedral Cu^I^ atoms into a zigzag chain; the Cu lies on a mirror plane that bisects the chelating biquinoline ligand.

Tetra-μ2-cyano-κ8C:N-μ2-2,6-dimethyl­pyr
Tetra-μ2-cyano-κ8C:N-μ2-2,6-dimethyl­pyrazine-κ2N:N′-hexa­kis(2,6-dimethyl­pyrazine-κN)octa-μ2-thio­cyanato-κ16N:S-deca­copper(I,II)
✍ Jess, Inke ;Näther, Christian 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 330 KB

The asymmetric unit of the title compound [Cu~8~ ^I^Cu~2~ ^II^(CN)~4~(NCS)~8~(C~6~H~8~N~2~)~7~], consists of six crystallographically independent Cu atoms, four thiocyanate anions and two cyanide anions, as well as four 2,6-dimethylpyrazine ligands. Two of the six Cu atoms and one of the four 2,6-di

catena-Poly[benzyl­triethyl­ammonium [tr
catena-Poly[benzyl­triethyl­ammonium [tri-μ-thio­cyanato-κ4N:S;κ2S:N-cadmate(II)]]
✍ Russo, Luca ;Sharma, Raj Pal ;Sharma, Subhranshu ;Sharma, Rajni ;Rissanen, Kari 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 321 KB

The title compound, {[(C 6 H 5 CH 2 )N(C 2 H 5 ) 3 ][Cd(SCN) 3 ]} n , contains benzyltriethylammonium cations lying between one-dimensional chains of stoichiometry {[Cd(SCN) 3 ] À } n . Each Cd 2+ ion is 3N,3S-hexacoordinated by thiocyanate ligands in an octahedral arrangement. The asymmetric unit c