𝔖 Bobbio Scriptorium
✦   LIBER   ✦

catena-Poly[benzyl­triethyl­ammonium [tri-μ-thio­cyanato-κ4N:S;κ2S:N-cadmate(II)]]

✍ Scribed by Russo, Luca ;Sharma, Raj Pal ;Sharma, Subhranshu ;Sharma, Rajni ;Rissanen, Kari

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
321 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, {[(C 6 H 5 CH 2 )N(C 2 H 5 ) 3 ][Cd(SCN) 3 ]} n , contains benzyltriethylammonium cations lying between one-dimensional chains of stoichiometry {[Cd(SCN) 3 ] À } n . Each Cd 2+ ion is 3N,3S-hexacoordinated by thiocyanate ligands in an octahedral arrangement. The asymmetric unit contains one cation and one anion.

📜 SIMILAR VOLUMES

catena-Poly[[bis(3-amino­benzoic acid-κN
catena-Poly[[bis(3-amino­benzoic acid-κN)­cadmium(II)]-di-μ-thio­cyanato-κ4N:S;S:N]
✍ Wang, Ruihu ;Hong, Maochun ;Luo, Junhua ;Han, Lei ;Lin, Zhenzhong ;Cao, Rong 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 334 KB

The title compound, [Cd("-SCN) 2 (C 7 H 7 NO 2 ) 2 ] n , has been prepared from the reaction of 3-aminobenzoic acid, NH 4 SCN and Cd(NO 3 ) 2 Á6H 2 O in MeOH/H 2 O. It consists of onedimensional polymeric chains, which are extended into a two-dimensional layer structure by head-to-head hydrogen bond

catena-Poly[[bis­(thio­cyanato-κN)cobalt
catena-Poly[[bis­(thio­cyanato-κN)cobalt(II)]-di-μ-2-amino­benzonitrile-κ2N,N′]
✍ Moitsheki, Lesego J. ;Bourne, Susan A. ;Nassimbeni, Luigi R. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 207 KB

Reaction of Co(NCS) 2 and 2-aminobenzonitrile (ABN) produces the title one-dimensional polymer, [Co(NCS) 2 -(ABN) 2 ] n , where ABN is 2-aminobenzonitrile (C 7 H 6 N 2 ). Octahedrally coordinated Co II ions are bridged by the ABN molecules, which are coordinated to the central metal via the N donors

Poly­[[(2-iodo­pyrazine-κN4)copper(I)]-μ
Poly­[[(2-iodo­pyrazine-κN4)copper(I)]-μ3-thio­cyanato-κ3N:S:S]
✍ Näther, Christian ;Wriedt, Mario ;Jeß, Inke 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 581 KB

In the crystal structure of the title compound, [Cu(NCS)-(C 4 H 3 IN 2 )] n , each Cu atom is coordinated by three thiocyanate anions and one 2-iodopyrazine ligand within a distorted tetrahedron. The Cu-coordinated units form dimers, which are connected into layers by the thiocyanate anions.

catena-Poly[[(di-2-pyridylamine-κ2N,N′)c
catena-Poly[[(di-2-pyridylamine-κ2N,N′)copper(I)]-μ-isothio­cyanato-κ2S:S]
✍ Zhou, Rui ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 184 KB

The NCS ligand in the title compound, [Cu(NCS)(C 10 H 9 N 3 )] n , bridges adjacent tetrahedral Cu I atoms through the sulfur end into a linear chain that runs along the b axis of the orthorhombic unit cell.