The title compound, [Cd("-SCN) 2 (C 7 H 7 NO 2 ) 2 ] n , has been prepared from the reaction of 3-aminobenzoic acid, NH 4 SCN and Cd(NO 3 ) 2 Á6H 2 O in MeOH/H 2 O. It consists of onedimensional polymeric chains, which are extended into a two-dimensional layer structure by head-to-head hydrogen bond
catena-Poly[[di-μ-thiocyanato-κ4S:S-argentate(I)]-di-μ-thiocyanato-κ4S:N-bis[diamminecopper(II)]-di-μ-thiocyanato-κ4N:S]
✍ Scribed by Liu, Dong-Sheng ;Liu, Su-Fang ;Xu, Ya-Ping ;Huang, Gan-Sheng ;Li, Xin-Fa
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 259 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The title compound, {[(C 6 H 5 CH 2 )N(C 2 H 5 ) 3 ][Cd(SCN) 3 ]} n , contains benzyltriethylammonium cations lying between one-dimensional chains of stoichiometry {[Cd(SCN) 3 ] À } n . Each Cd 2+ ion is 3N,3S-hexacoordinated by thiocyanate ligands in an octahedral arrangement. The asymmetric unit c
Reaction of Co(NCS) 2 and 2-aminobenzonitrile (ABN) produces the title one-dimensional polymer, [Co(NCS) 2 -(ABN) 2 ] n , where ABN is 2-aminobenzonitrile (C 7 H 6 N 2 ). Octahedrally coordinated Co II ions are bridged by the ABN molecules, which are coordinated to the central metal via the N donors
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