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A non-centrosymmetric one-dimensional coordination polymer: catena[[(4,7-phenanthrolin-4-ium-κN7)(thiocyanato-κS)copper(I)]-μ-thiocyanato-κ2N:S]

✍ Scribed by Schottenfeld, Jodi ;Rarig, Randy S. ;Zubieta, Jon ;LaDuca, Robert L.

Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 384 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536806054249

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Poly[[(2-iodopyrazine-κN4)copper(I)]-μ

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In the crystal structure of the title compound, [Cu(NCS)-(C 4 H 3 IN 2 )] n , each Cu atom is coordinated by three thiocyanate anions and one 2-iodopyrazine ligand within a distorted tetrahedron. The Cu-coordinated units form dimers, which are connected into layers by the thiocyanate anions.

A coordination polymer with conformation

A coordination polymer with conformationally distinct layers: poly[(μ-1,3-di-4-pyridylpropane-κ2N:N′)bis(μ3-thiocyanato-κ3N,S:S)dicopper(I)]

✍ Trovitch, Ryan J. ;Rarig, Randy S. ;Zubieta, Jon A. ;LaDuca, Robert L. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 552 KB

A non-centrosymmetric one-dimensional coordination polymer: catena[[(4,7-phenanthrolin-4-ium-κN7)(thio­cyanato-κS)copper(I)]-μ-thio­cyanato-κ2N:S]

A non-centrosymmetric one-dimensional coordination polymer: catena[[(4,7-phenanthrolin-4-ium-κN7)(thiocyanato-κS)copper(I)]-μ-thiocyanato-κ2N:S]