catena-Poly[[bis(3-aminobenzoic acid-κN)cadmium(II)]-di-μ-thiocyanato-κ4N:S;S:N]
✍ Scribed by Wang, Ruihu ;Hong, Maochun ;Luo, Junhua ;Han, Lei ;Lin, Zhenzhong ;Cao, Rong
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 334 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [Cd("-SCN) 2 (C 7 H 7 NO 2 ) 2 ] n , has been prepared from the reaction of 3-aminobenzoic acid, NH 4 SCN and Cd(NO 3 ) 2 Á6H 2 O in MeOH/H 2 O. It consists of onedimensional polymeric chains, which are extended into a two-dimensional layer structure by head-to-head hydrogen bonds involving carboxyl groups from adjacent chains.
📜 SIMILAR VOLUMES
Reaction of Co(NCS) 2 and 2-aminobenzonitrile (ABN) produces the title one-dimensional polymer, [Co(NCS) 2 -(ABN) 2 ] n , where ABN is 2-aminobenzonitrile (C 7 H 6 N 2 ). Octahedrally coordinated Co II ions are bridged by the ABN molecules, which are coordinated to the central metal via the N donors
The title compound, {[(C 6 H 5 CH 2 )N(C 2 H 5 ) 3 ][Cd(SCN) 3 ]} n , contains benzyltriethylammonium cations lying between one-dimensional chains of stoichiometry {[Cd(SCN) 3 ] À } n . Each Cd 2+ ion is 3N,3S-hexacoordinated by thiocyanate ligands in an octahedral arrangement. The asymmetric unit c
In the crystal structure of the title compound, [Cu(NCS)-(C 4 H 3 IN 2 )] n , each Cu atom is coordinated by three thiocyanate anions and one 2-iodopyrazine ligand within a distorted tetrahedron. The Cu-coordinated units form dimers, which are connected into layers by the thiocyanate anions.