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catena-Poly[[bis­(thio­cyanato-κN)cobalt(II)]-di-μ-2-amino­benzonitrile-κ2N,N′]

✍ Scribed by Moitsheki, Lesego J. ;Bourne, Susan A. ;Nassimbeni, Luigi R.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
207 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

Reaction of Co(NCS) 2 and 2-aminobenzonitrile (ABN) produces the title one-dimensional polymer, [Co(NCS) 2 -(ABN) 2 ] n , where ABN is 2-aminobenzonitrile (C 7 H 6 N 2 ). Octahedrally coordinated Co II ions are bridged by the ABN molecules, which are coordinated to the central metal via the N donors of the cyano and nitrile groups.

📜 SIMILAR VOLUMES

catena-Poly[[bis(3-amino­benzoic acid-κN
catena-Poly[[bis(3-amino­benzoic acid-κN)­cadmium(II)]-di-μ-thio­cyanato-κ4N:S;S:N]
✍ Wang, Ruihu ;Hong, Maochun ;Luo, Junhua ;Han, Lei ;Lin, Zhenzhong ;Cao, Rong 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 334 KB

The title compound, [Cd("-SCN) 2 (C 7 H 7 NO 2 ) 2 ] n , has been prepared from the reaction of 3-aminobenzoic acid, NH 4 SCN and Cd(NO 3 ) 2 Á6H 2 O in MeOH/H 2 O. It consists of onedimensional polymeric chains, which are extended into a two-dimensional layer structure by head-to-head hydrogen bond

catena-Poly[[bis(thiocyanato-κN)cobalt(I
catena-Poly[[bis(thiocyanato-κN)cobalt(II)]-μ-di-4-pyridylamine-κ2N:N′]
✍ Springsteen, Caleb H. ;LaDuca, Robert L. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 943 KB

In the title compound, [Co(NCS)~2~(C~10~H~9~N~3~)], a Co^II^ atom with tetrahedral coordination is bound by two __N__-donor thiocyanate anions and two __N__-donor atoms from two crystallographically distinct di-4-pyridylamine (dpa) ligands whose central NH units lie on twofold axes. The dpa ligands