Bis(thiocyanato-κN)bis(2,2′-thiodipyridine-κ2N,N′)nickel(II) monohydrate
✍ Scribed by Zhao, Qi-Hua ;Mu, Xiu-Mei ;Zhang, Mei-Su ;Fang, Rui-Bing
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 151 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Bis(thiocyanato-jN)bis(2,2 0 0 0 -thiodipyridine-j 2 N,N 0 0 0 )nickel(II) monohydrate
📜 SIMILAR VOLUMES
Reaction of Co(NCS) 2 and 2-aminobenzonitrile (ABN) produces the title one-dimensional polymer, [Co(NCS) 2 -(ABN) 2 ] n , where ABN is 2-aminobenzonitrile (C 7 H 6 N 2 ). Octahedrally coordinated Co II ions are bridged by the ABN molecules, which are coordinated to the central metal via the N donors
The title complex, [Co(NCS) 2 (C 8 H 8 N 2 O) 2 ], possesses crystallographically imposed twofold symmetry. The Co II atom is coordinated by four N atoms and two O atoms in a distorted octahedral geometry. The crystal packing is stabilized by weak intermolecular O-HÁ Á ÁS and N-HÁ Á ÁS hydrogen bond
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.039 wR factor = 0.078 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 193 K Mean '(C±C) = 0.005 A Ê R factor = 0.055 wR factor = 0.101 Data-to-parameter ratio = 17.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.038 wR factor = 0.099 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.