In the title complex, [Cd(NCS) 2 (C 5 H 5 N) 4 ], the Cd II atom lies on a center of inversion. It is coordinated by four N atoms from four pyridines and two N atoms from two isothiocyanate ions and has a slightly distorted octahedral geometry.
Bis(isothiocyanato-κN)bis[8-(methoxycarbonylmethoxy)quinoline-κN]copper(II)
✍ Scribed by Song, Rui-Feng ;Wang, Yu-Hong ;Jiang, Fan
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 273 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 193 K Mean '(C±C) = 0.005 A Ê R factor = 0.055 wR factor = 0.101 Data-to-parameter ratio = 17.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
Bis(thiocyanato-jN)bis(2,2 0 0 0 -thiodipyridine-j 2 N,N 0 0 0 )nickel(II) monohydrate
catena-Poly [[bis(isothiocyanato-jN)copper(II)]bis(l-1,1 0 0 0 -methylenedi-1H-imidazole-jN 3 :jN 3 0 0 0
The title complex, [Co(NCS) 2 (C 8 H 8 N 2 O) 2 ], possesses crystallographically imposed twofold symmetry. The Co II atom is coordinated by four N atoms and two O atoms in a distorted octahedral geometry. The crystal packing is stabilized by weak intermolecular O-HÁ Á ÁS and N-HÁ Á ÁS hydrogen bond
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.039 wR factor = 0.078 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.