trans-Bis(isothiocyanato-κN)tetrapyridinecadmium(II)
✍ Scribed by Qu, Yang ;Liu, Zhao-Di ;Zhu, Hai-Liang ;Tan, Min-Yu
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 280 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, [Cd(NCS) 2 (C 5 H 5 N) 4 ], the Cd II atom lies on a center of inversion. It is coordinated by four N atoms from four pyridines and two N atoms from two isothiocyanate ions and has a slightly distorted octahedral geometry.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 193 K Mean '(C±C) = 0.005 A Ê R factor = 0.055 wR factor = 0.101 Data-to-parameter ratio = 17.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Bis(thiocyanato-jN)bis(2,2 0 0 0 -thiodipyridine-j 2 N,N 0 0 0 )nickel(II) monohydrate
In the title compound, [Zn(NCS) 2 (H 2 O) 4 ]Á2C 5 H 6 N 2 O 2 , the six-coordinated Zn II atom lies on a special position of site symmetry 2/m. The methylpyrazine dioxide molecule lies on a mirror plane and links with the Zn II complex via O-HÁ Á ÁO hydrogen bonding.