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cis-Bis[(1H-benzimidazol-2-yl)methanol-κ2N,O]bis­(thio­cyanato-κN)cobalt(II)

✍ Scribed by Zeng, Ming-Hua ;Zhou, Yan-Ling ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
136 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title complex, [Co(NCS) 2 (C 8 H 8 N 2 O) 2 ], possesses crystallographically imposed twofold symmetry. The Co II atom is coordinated by four N atoms and two O atoms in a distorted octahedral geometry. The crystal packing is stabilized by weak intermolecular O-HÁ Á ÁS and N-HÁ Á ÁS hydrogen bonds.

📜 SIMILAR VOLUMES

Bis[2-(benzimidazol-2-yl)phenolato-κ2N,O
Bis[2-(benzimidazol-2-yl)phenolato-κ2N,O]cobalt(II)
✍ Bu, Huai-Yu ;Liu, Yong-Jun ;Liu, Qing-Fang ;Jia, Jing-Fen 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 139 KB

In the title compound, [Co(C 13 H 9 N 2 O) 2 ], the coordination geometry of the Co II atom is distorted tetrahedral; the Co atom lies on a twofold axis. Adjacent molecules are linked by N-HÁ Á ÁO hydrogen bonds into a three-dimensional network structure.

Bis[1,3-bis(1H-benzimidazol-2-yl)benzene
Bis[1,3-bis(1H-benzimidazol-2-yl)benzene-κN3]bis(nitrato-κ2O,O′)cadmium(II) dihydrate
✍ Meng, Fa-Yan ;Zhang, Yi-Ming ;Ng, Seik Weng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 403 KB

In the title complex, [Cd(NO~3~)~2~(C~20~H~14~N~4~)~2~]·2H~2~O, the Cd^II^ ion, which lies on a crystallographic twofold axis, is bis-chelated by two nitrate ligands and is coordinated by one tertiary N atom from each of two 1,3-bis(1__H__-benzimidazol-2-ylmethyl)benzene ligands in a distorted octah