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Bis[2-(benzimidazol-2-yl)phenolato-κ2N,O]cobalt(II)

✍ Scribed by Bu, Huai-Yu ;Liu, Yong-Jun ;Liu, Qing-Fang ;Jia, Jing-Fen


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
139 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [Co(C 13 H 9 N 2 O) 2 ], the coordination geometry of the Co II atom is distorted tetrahedral; the Co atom lies on a twofold axis. Adjacent molecules are linked by N-HÁ Á ÁO hydrogen bonds into a three-dimensional network structure.


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cis-Bis[(1H-benzimidazol-2-yl)methanol-κ
✍ Zeng, Ming-Hua ;Zhou, Yan-Ling ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 136 KB

The title complex, [Co(NCS) 2 (C 8 H 8 N 2 O) 2 ], possesses crystallographically imposed twofold symmetry. The Co II atom is coordinated by four N atoms and two O atoms in a distorted octahedral geometry. The crystal packing is stabilized by weak intermolecular O-HÁ Á ÁS and N-HÁ Á ÁS hydrogen bond