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Bis[2-(benzimidazol-2-yl)phenolato-κ2N,O]zinc(II)–bis­[5-amino-2-(benzimidazol-2-yl)phenolato-κ2N,O]zinc(II)–ethanol–water (0.56/0.44/2/0.5)

✍ Scribed by Tong, Yi-Ping

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
289 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

Bis[2-(benzimidazol-2-yl)phenolato-j 2 N,O]zinc(II)-bis[5-amino-2-(benzimidazol-2-yl)phenolato-j 2 N,O]zinc(II)-ethanol-water (0.56/0.44/2/0.5

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In the title compound, [Co(C 13 H 9 N 2 O) 2 ], the coordination geometry of the Co II atom is distorted tetrahedral; the Co atom lies on a twofold axis. Adjacent molecules are linked by N-HÁ Á ÁO hydrogen bonds into a three-dimensional network structure.

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Bis[2-(2-naphthyliminomethyl)phenolato-κ2N,O]zinc(II)
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In the title complex, [Zn(C 17 H 12 NO) 2 ], the Zn II ion is coordinated by two N,O-bidentate ligand molecules in a distorted tetrahedral geometry. The crystal packing may be stabilized by weak C-HÁ Á ÁCg interactions [Cg is a ring centroid; HÁ Á ÁCg = 2.95 A ˚].

Bis[2-(1H-imidazol-2-yl)phenolato-κ2N,O]
Bis[2-(1H-imidazol-2-yl)phenolato-κ2N,O]zinc(II) methanol solvate
✍ He, Hong-Shan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 184 KB

In the title complex, [Zn(C 18 H 14 N 4 O 2 )]ÁCH 3 OH, two anionic 2-(1H-imidazol-2-yl)phenolate bidentate ligands coordinate through the phenolate O and imidazolyl N atoms to the central Zn II atom to give a four-coordinate tetrahedral geometry.