catena-Poly[[bis(4-chloromethylpyridine-κN)cobalt(II)]-di-μ-dicyanamido-κ2N1:κ2N5]
✍ Scribed by Pei, Hong-Xia ;Sun, Yu-Xi ;Lu, She-Ming ;Li, Jian-Min ;Wu, Xin-Tao ;Du, Wen-Xin
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 208 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Co(NCS)~2~(C~10~H~9~N~3~)], a Co^II^ atom with tetrahedral coordination is bound by two __N__-donor thiocyanate anions and two __N__-donor atoms from two crystallographically distinct di-4-pyridylamine (dpa) ligands whose central NH units lie on twofold axes. The dpa ligands
Reaction of Co(NCS) 2 and 2-aminobenzonitrile (ABN) produces the title one-dimensional polymer, [Co(NCS) 2 -(ABN) 2 ] n , where ABN is 2-aminobenzonitrile (C 7 H 6 N 2 ). Octahedrally coordinated Co II ions are bridged by the ABN molecules, which are coordinated to the central metal via the N donors
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.004 A Ê R factor = 0.027 wR factor = 0.071 Data-to-parameter ratio = 11.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.