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catena-Poly[[bis(thiocyanato-κN)cobalt(II)]-μ-di-4-pyridylamine-κ2N:N′]

✍ Scribed by Springsteen, Caleb H. ;LaDuca, Robert L.

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 943 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807049276

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✦ Synopsis

In the title compound, [Co(NCS)~2~(C~10~H~9~N~3~)], a Co^II^ atom with tetrahedral coordination is bound by two N-donor thiocyanate anions and two N-donor atoms from two crystallographically distinct di-4-pyridylamine (dpa) ligands whose central NH units lie on twofold axes. The dpa ligands link the Co atoms into one-dimensional [Co(NCS)~2~(dpa)]~n~ coordination polymer chains that propagate along the b-axis direction.

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