The title compound, [Cd(C 2 H 6 O 2 PS 2 ) 2 (C 10 H 8 N 2 )] n , contains zigzag chains linked through the 4,4 H -bipyridine groups. The Cd atom exhibits a slightly distorted octahedral coordination environment, consisting of four S atoms of the chelating dimethyl dithiophosphate ligands and two N
catena-Poly[[bis(O,O′-diethyl dithiophosphato-κ2S,S′)cadmium(II)]-μ-4,4′-bipyridine-N:N′]
✍ Scribed by Li, Tao ;Li, Zhi-Hua ;Du, Shao-Wu
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 164 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The Ni atom in the linear polymeric title complex, [Ni{S~2~P(OC~6~H~11~)~2~}~2~(NC~5~H~4~C~5~H~4~N)]~__n__~ or [Ni(C~12~H~22~O~2~PS~2~)~2~(C~10~H~8~N~2~)]~__n__~, is octahedrally coordinated within a __trans__-N~2~S~4~ donor set. The Ni atom and the N atoms of the 4,4′-bipyridine ligand are located
In the zigzag polymeric title compound, [Zn(S~2~P(OEt)~2~)~2~(NC~5~H~4~CH)~2~CH~2~C~5~H~4~N)]~__n__~ or [Zn(C~4~H~10~O~2~PS~2~)~2~(C~12~H~12~N~2~)]~__n__~, the Zn atom adopts a distorted tetrahedral ZnN~2~S~2~ geometry; the bridging di-4-pyridylethane molecules are each disposed about a centre of in
Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.003 A Ê R factor = 0.036 wR factor = 0.093 Data-to-parameter ratio = 27.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
catena-Poly[[bis(O,O 0 0 0 -dicyclohexyldithiophosphato-j 2 ,S,S 0 0 0 )zinc(II)]-l-1,2-bis(4pyridylmethylene)hydrazine-j 2 N:N 0 0 0 ]