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catena-Poly[[bis­(O,O′-diethyl dithio­phosphato-κ2S,S′)zinc(II)]-μ-1,2-di-4-pyridylethane-κ2N:N′]

✍ Scribed by Tiekink, Edward R. T. ;Wardell, James L. ;Welte, William B.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
256 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the zigzag polymeric title compound, [Zn(S~2~P(OEt)~2~)~2~(NC~5~H~4~CH)~2~CH~2~C~5~H~4~N)]~n~ or [Zn(C~4~H~10~O~2~PS~2~)~2~(C~12~H~12~N~2~)]~n~, the Zn atom adopts a distorted tetrahedral ZnN~2~S~2~ geometry; the bridging di-4-pyridylethane molecules are each disposed about a centre of inversion.

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Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.003 A Ê R factor = 0.036 wR factor = 0.093 Data-to-parameter ratio = 27.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.