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catena-Poly[[bis­(O,O′-diisopropyl dithiophosphato-κ2S,S′)zinc(II)]-μ-1,2-di-4-pyridylethyl­ene-κ2N:N′]

✍ Scribed by Welte, William B. ;Tiekink, Edward R. T.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
341 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the zigzag polymeric title compound, [Zn{S~2~P(O^i^Pr)~2~}~2~{NC~5~H~4~C(H)=C(H)C~5~H~4~N}]~n~ or [Zn(C~6~H~14~O~2~PS~2~)~2~(C~12~H~10~N~2~)]~n~, the Zn atom adopts a distorted tetrahedral ZnN~2~S~2~ geometry.

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Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.003 A Ê R factor = 0.036 wR factor = 0.093 Data-to-parameter ratio = 27.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.