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μ-1,4-Diaza­bicyclo­[2.2.2]octane-κ2N:N′-bis­[bis­(O,O′-diisopropyl dithio­phosphato-κ2S,S′)zinc(II)]

✍ Scribed by Ellis, Carol A. ;Ng, Seik Weng ;Tiekink, Edward R. T.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
211 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

l-1,4-Diazabicyclo[2.2.2]octane-j 2 N:N 0 0 0 -bis[bis-(O,O 0 0 0 -diisopropyl dithiophosphato-j 2 S,S 0 0 0 )zinc(II)]

📜 SIMILAR VOLUMES

μ-1,4-Diaza­bicyclo­[2.2.2]octane-κ2N:N′
μ-1,4-Diaza­bicyclo­[2.2.2]octane-κ2N:N′-bis­[bis­(O,O′-dicyclo­hexyl dithio­phosphato-κ2S,S′)cadmium(II)]
✍ Ellis, Carol A. ;Ng, Seik Weng ;Tiekink, Edward R. T. ;Wardell, James L. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 186 KB

The dinuclear title molecule, [Cd~2~(C~12~H~22~O~2~PS~2~)~4~(C~6~H~12~N~2~)], is disordered and located on a centre of inversion, and features a coordination geometry intermediate between square-pyramidal and trigonal-bipyramidal.

catena-Poly[[bis­(O,O′-diethyl dithio­ph
catena-Poly[[bis­(O,O′-diethyl dithio­phosphato-κ2S,S′)zinc(II)]-μ-1,2-di-4-pyridylethane-κ2N:N′]
✍ Tiekink, Edward R. T. ;Wardell, James L. ;Welte, William B. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 256 KB

In the zigzag polymeric title compound, [Zn(S~2~P(OEt)~2~)~2~(NC~5~H~4~CH)~2~CH~2~C~5~H~4~N)]~__n__~ or [Zn(C~4~H~10~O~2~PS~2~)~2~(C~12~H~12~N~2~)]~__n__~, the Zn atom adopts a distorted tetrahedral ZnN~2~S~2~ geometry; the bridging di-4-pyridylethane molecules are each disposed about a centre of in

catena-Poly­[[bis(O,O′-diiso­butyldi­thi
catena-Poly­[[bis(O,O′-diiso­butyldi­thio­phosphato-κ2S,S′)­zinc(II)]-μ-1,2-bis(4-pyridyl)­ethane-κ2N:N′]
✍ Lai, Chian Sing ;Liu, Sikai ;Tiekink, Edward R. T. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 295 KB

Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.003 A Ê R factor = 0.036 wR factor = 0.093 Data-to-parameter ratio = 27.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.