(2,2′-Bipyridyl-κ2N,N′)bis(O,O′-diisopropyl dithiophosphato-κ2S,S′)nickel(II)
✍ Scribed by Berdugo, Erick ;Tiekink, Edward R. T. ;Wardell, James L. ;Wardell, Solange M. S. V.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 253 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
l-1,4-Diazabicyclo[2.2.2]octane-j 2 N:N 0 0 0 -bis[bis-(O,O 0 0 0 -diisopropyl dithiophosphato-j 2 S,S 0 0 0 )zinc(II)]
The dinuclear title molecule, [Cd~2~(C~12~H~22~O~2~PS~2~)~4~(C~6~H~12~N~2~)], is disordered and located on a centre of inversion, and features a coordination geometry intermediate between square-pyramidal and trigonal-bipyramidal.
In the zigzag polymeric title compound, [Zn(S~2~P(OEt)~2~)~2~(NC~5~H~4~CH)~2~CH~2~C~5~H~4~N)]~__n__~ or [Zn(C~4~H~10~O~2~PS~2~)~2~(C~12~H~12~N~2~)]~__n__~, the Zn atom adopts a distorted tetrahedral ZnN~2~S~2~ geometry; the bridging di-4-pyridylethane molecules are each disposed about a centre of in
The Ni atom in the monomeric title compound, [Ni(C~6~H~14~O~2~PS~2~)~2~(C~12~H~8~N~2~)], is within a distorted octahedral N~2~S~4~ geometry, defined by two chelating dithiophosphate ligands and a chelating 1,10-phenanthroline ligand.