𝔖 Bobbio Scriptorium
✦   LIBER   ✦

μ-1,4-Diaza­bicyclo­[2.2.2]octane-κ2N:N′-bis­[bis­(O,O′-dicyclo­hexyl dithio­phosphato-κ2S,S′)cadmium(II)]

✍ Scribed by Ellis, Carol A. ;Ng, Seik Weng ;Tiekink, Edward R. T. ;Wardell, James L.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
186 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The dinuclear title molecule, [Cd~2~(C~12~H~22~O~2~PS~2~)~4~(C~6~H~12~N~2~)], is disordered and located on a centre of inversion, and features a coordination geometry intermediate between square-pyramidal and trigonal-bipyramidal.

📜 SIMILAR VOLUMES

catena-Poly[[bis­(O,O′-diethyl dithio­ph
catena-Poly[[bis­(O,O′-diethyl dithio­phosphato-κ2S,S′)zinc(II)]-μ-1,2-di-4-pyridylethane-κ2N:N′]
✍ Tiekink, Edward R. T. ;Wardell, James L. ;Welte, William B. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 256 KB

In the zigzag polymeric title compound, [Zn(S~2~P(OEt)~2~)~2~(NC~5~H~4~CH)~2~CH~2~C~5~H~4~N)]~__n__~ or [Zn(C~4~H~10~O~2~PS~2~)~2~(C~12~H~12~N~2~)]~__n__~, the Zn atom adopts a distorted tetrahedral ZnN~2~S~2~ geometry; the bridging di-4-pyridylethane molecules are each disposed about a centre of in

catena-Poly[[bis(O,O′-dimethyl dithio­ph
catena-Poly[[bis(O,O′-dimethyl dithio­phosphato-κ2S,S′)cadmium(II)]-μ-4,4'-bipyridine-N:N′]
✍ Li, Tao ;LI, Zhi-Hua ;Du, Shao-Wu 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 259 KB

The title compound, [Cd(C 2 H 6 O 2 PS 2 ) 2 (C 10 H 8 N 2 )] n , contains zigzag chains linked through the 4,4 H -bipyridine groups. The Cd atom exhibits a slightly distorted octahedral coordination environment, consisting of four S atoms of the chelating dimethyl dithiophosphate ligands and two N