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catena-Poly[[bis­(O,O′-dicyclo­hexyldithio­phosphato-κ2,S,S′)zinc(II)]-μ-1,2-bis­(4-pyridylmethyl­ene)hydrazine-κ2N:N′]

✍ Scribed by Chen, Danlin ;Lai, Chian Sing ;Tiekink, Edward R. T.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
270 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

catena-Poly[[bis(O,O 0 0 0 -dicyclohexyldithiophosphato-j 2 ,S,S 0 0 0 )zinc(II)]-l-1,2-bis(4pyridylmethylene)hydrazine-j 2 N:N 0 0 0 ]

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The Ni atom in the linear polymeric title complex, [Ni{S~2~P(OC~6~H~11~)~2~}~2~(NC~5~H~4~C~5~H~4~N)]~__n__~ or [Ni(C~12~H~22~O~2~PS~2~)~2~(C~10~H~8~N~2~)]~__n__~, is octahedrally coordinated within a __trans__-N~2~S~4~ donor set. The Ni atom and the N atoms of the 4,4′-bipyridine ligand are located