In the zigzag polymeric title compound, [Zn{S~2~P(O^i^Pr)~2~}~2~{NC~5~H~4~C(H)=C(H)C~5~H~4~N}]~__n__~ or [Zn(C~6~H~14~O~2~PS~2~)~2~(C~12~H~10~N~2~)]~__n__~, the Zn atom adopts a distorted tetrahedral ZnN~2~S~2~ geometry.
catena-Poly[[dichlorozinc(II)]-μ-1,2-di-4-pyridylethylene-κ2N:N′]
✍ Scribed by Qin, Chuang-Ye ;Xu, Jing-Wei
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 129 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [ZnCl~2~(C~12~H~10~N~2~)]~n~, the Zn^II^ ion displays a tetrahedral coordination geometry. Each 1,2-di-4-pyridylethylene ligand is located on an inversion center and bridges Zn^II^ ions, forming a zigzag polymeric chain. Weak C—H...Cl hydrogen bonding is observed in the crystal structure.
📜 SIMILAR VOLUMES
The title compound, [NiCl 2 (C 12 H 12 N 2 )] n , is a nickel complex polymer bridged by 1,2-bis(4-pyridyl)ethane ligands. The Ni II center is coordinated in a distorted tetrahedral geometry by two Cl ligands and two N atoms from two 1,2-bis(4-pyridyl)ethane ligands, forming a one-dimensional zigzag
The title compound, [Nd(C~2~HCl~2~O~2~)~3~(C~10~H~8~N~2~)]~__n__~, was synthesized by reaction of neodymium(III) dichloroacetate with 2,2′-bipyridine in a water–ethanol (1:1) solution. The structure consists of chains running along the __a__ axis. The Nd^3+^ ions are coordinated by seven O and two N