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catena-Poly[[μ-1,2-di-4-pyridylethyl­ene-κ2N,N′-[aqua­(2-sulfonatobenzoato-κ2O,O′)copper(II)]] N,N-dimethyl­formamide]

✍ Scribed by Xiao, Hong-Ping ;Shi, Qian ;Cheng, Ya-Qian

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
204 KB
Volume
61
Category
Article
ISSN
1600-5368

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✍ Xiao, Hong-Ping 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 196 KB

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In the title compound, [ZnCl~2~(C~12~H~10~N~2~)]~__n__~, the Zn^II^ ion displays a tetrahedral coordination geometry. Each 1,2-di-4-pyridylethylene ligand is located on an inversion center and bridges Zn^II^ ions, forming a zigzag polymeric chain. Weak C—H...Cl hydrogen bonding is observed in the cr

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In the zigzag polymeric title compound, [Zn{S~2~P(O^i^Pr)~2~}~2~{NC~5~H~4~C(H)=C(H)C~5~H~4~N}]~__n__~ or [Zn(C~6~H~14~O~2~PS~2~)~2~(C~12~H~10~N~2~)]~__n__~, the Zn atom adopts a distorted tetrahedral ZnN~2~S~2~ geometry.