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catena-Poly[[[diaqua­(2-sulfonatobenzoato-κ2O:O′)zinc(II)]-μ2-1,3-di-4-pyridylpropane-κ2N:N′] N,N-dimethyl­formamide solvate]

✍ Scribed by Xiao, Hong-Ping

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
196 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Zn(C~7~H~4~O~5~S)(C~13~H~14~N~2~)(H~2~O)~2~]·C~3~H~7~NO, the Zn^II^ atom is coordinated by two N atoms from two 1,3-di-4-pyridylpropane molecules, two O atoms from one 2-sulfonatobenzoate dianion and two aqua O atoms, in a distorted octahedral geometry. The 2-sulfonatobenzoate dianions function as chelating ligands and the 1,3-di-4-pyridylpropane as a μ~2~-bridging ligand, forming a chain. O—H...O hydrogen bonds link neighbouring chains into a three-dimensional network.

📜 SIMILAR VOLUMES

Poly[(μ2-1,3-di-4-pyridylpropane-κ2N:N′)
Poly[(μ2-1,3-di-4-pyridylpropane-κ2N:N′)(μ2-terephthalato-κ2O:O′)zinc(II)]
✍ Yang, E ;Song, Xu-Chun ;Lin, You-Dan ;Shen, Shuang-Zhen 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 1016 KB

In the title compound, [Zn(C 8 H 4 O 4 )(C 13 H 14 N 2 )] n , each Zn atom is coordinated by two terephthalate and two 1,3-di-4pyridylpropane ligands in a distorted tetrahedral fashion. As a result, undulating layers are formed perpendicular to the b axis. ## Related literature For related litera

catena-Poly[[[diaqua­bis(N,N-dimethyl­fo
catena-Poly[[[diaqua­bis(N,N-dimethyl­formamide)­cobalt(II)]-μ-1,4-benzene­dicarboxyl­ato-κ2O:O′] N,N-dimethyl­formamide solvate monohydrate]
✍ Jia, Chun-Xiao 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 257 KB

Single-crystal X-ray study T = 294 K Mean (C-C) = 0.004 A R factor = 0.044 wR factor = 0.125 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.