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catena-Poly[[bis(O-isopropyl dithiocarbonato-κ2S,S′)nickel(II)]-μ-1,2-di-4-pyridylethane-κ2N:N′]

✍ Scribed by Hill, Denise D. ;Tiekink, Edward R. T.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
425 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The Ni atom in the zigzag polymeric title complex, [Ni(C~4~H~7~OS~2~)~2~(C~12~H~12~N~2~)]~n~, is situated on a twofold axis and the bridging ligand situated about a centre of inversion. The structure features a distorted octahedral cis-NiN~2~S~4~ coordination geometry defined by two chelating O-isopropyl dithiocarbonate ligands and two N atoms derived from the bidentate bridging ligands.

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