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catena-Poly[[(2,2′-biquinoline-κ2N,N′)copper(I)]-μ-isothio­cyanato-κ2N:S]

✍ Scribed by Zhou, Rui ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
163 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The isothiocyanate ligand in the title compound, [Cu(NCS)(C~18~H~12~N~2~)]~n~, links adjacent tetrahedral Cu^I^ atoms into a zigzag chain; the Cu lies on a mirror plane that bisects the chelating biquinoline ligand.

📜 SIMILAR VOLUMES

catena-Poly[[(di-2-pyridylamine-κ2N,N′)c
catena-Poly[[(di-2-pyridylamine-κ2N,N′)copper(I)]-μ-isothio­cyanato-κ2S:S]
✍ Zhou, Rui ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 184 KB

The NCS ligand in the title compound, [Cu(NCS)(C 10 H 9 N 3 )] n , bridges adjacent tetrahedral Cu I atoms through the sulfur end into a linear chain that runs along the b axis of the orthorhombic unit cell.

catena-Poly[[bis­(thio­cyanato-κN)cobalt
catena-Poly[[bis­(thio­cyanato-κN)cobalt(II)]-di-μ-2-amino­benzonitrile-κ2N,N′]
✍ Moitsheki, Lesego J. ;Bourne, Susan A. ;Nassimbeni, Luigi R. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 207 KB

Reaction of Co(NCS) 2 and 2-aminobenzonitrile (ABN) produces the title one-dimensional polymer, [Co(NCS) 2 -(ABN) 2 ] n , where ABN is 2-aminobenzonitrile (C 7 H 6 N 2 ). Octahedrally coordinated Co II ions are bridged by the ABN molecules, which are coordinated to the central metal via the N donors

Poly[μ-1,3-thia­zolidine-2-thione-κ2S2:S
Poly[μ-1,3-thia­zolidine-2-thione-κ2S2:S2-μ-thio­cyanato-κ2S:N-copper(I)]
✍ Saithong, Saowanit ;Pakawatchai, Chaveng ;Charmant, Jonathan P. H. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 188 KB

The title compound, [Cu(SCN)(C~3~H~5~NS~2~)]~__n__~, was prepared from the direct reaction between copper(I) thiocyanate and 1,3-thiazolidine-2-thione. The structure is an infinite two-dimensional polymer, parallel to the __ac__ plane, with tetrahedrally distorted Cu atoms which are coordinated by t