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catena-Poly[[(di-2-pyridylamine-κ2N2,N2′)copper(II)]-μ-3,3′-dithio­dipropionato-κO,O′:κO′′]

✍ Scribed by Ren, Bao-Dong ;Zhao, Ya-Juan

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
330 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

)copper(II)]l-3,3 0 0 0 -dithiodipropionato-jO,O 0 0 0 :jO 0 0 00 0 0 ]

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In the title compound, [Cu(C~2~O~4~)(C~6~H~7~NO)~2~]~__n__~, the Cu^II^ atom is six-coordinated in a slightly deformed elongated octahedral arrangement and the 3-(hydroxymethyl)pyridine ligand, surprisingly, acts as a monodentate ligand coordinated only through the N atom of the pyridine ring. The o

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The polymeric structure of the title complex, [Cu(C~7~H~4~ClO~3~)~2~(C~6~H~7~NO)~2~]~__n__~, at 100 (2) K contains two-dimensional sheets parallel to the __ac__ plane. The Cu^II^ atom, lying on an inversion centre, has an octahedral coordination environment. It is bonded in a __trans__-square-planar