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catena-Poly[[bis(3-pyridylmethanol-κN)copper(II)]-μ-oxalato-1κ2O1,O2:2κ2O1′,O2′]

✍ Scribed by Jašková, Jana ;Mikloš, Dušan ;Segľa, Peter ;Sillanpää, Reijo ;Moncol, Jan

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 102 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807008471

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✦ Synopsis

In the title compound, [Cu(C~2~O~4~)(C~6~H~7~NO)~2~]~n~, the Cu^II^ atom is six-coordinated in a slightly deformed elongated octahedral arrangement and the 3-(hydroxymethyl)pyridine ligand, surprisingly, acts as a monodentate ligand coordinated only through the N atom of the pyridine ring. The oxalate ligands, on inversion centres, bridge the metal ions, forming infinite chains. The chains are linked by intermolecular O—H...O hydrogen bonds into a three-dimensional network.

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✦ Synopsis

catena-Poly[[bis(3-pyridylmethanol-κN)copper(II)]-μ-oxalato-1κ2O1,O2:2κ2O1′,O2′]