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μ-Oxalato-1κ2O,O′:2κ2O′′,O′′′-bis­(chloro{[1-(2-pyridyl-κN)ethyl­idene]hydrazine-κN}copper(II))

✍ Scribed by Tomyn, Stefaniya V. ;Gumienna-Kontecka, Elźbieta ;Fritsky, Igor O. ;Iskenderov, Turganbay S. ;Światek-Kozłowska, Jolanta


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
235 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


l-Oxalato-1j 2 O,O 0 0 0 :2j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis(chloro{[1-(2pyridyl-jN)ethylidene]hydrazine-jN}copper(II)


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In the title compound, [Cu(C~2~O~4~)(C~6~H~7~NO)~2~]~__n__~, the Cu^II^ atom is six-coordinated in a slightly deformed elongated octahedral arrangement and the 3-(hydroxymethyl)pyridine ligand, surprisingly, acts as a monodentate ligand coordinated only through the N atom of the pyridine ring. The o