In the title dimeric complex, [Cu~2~(C~2~O~4~)Cl~2~(C~12~H~8~N~2~)~2~], which lies on a crystallographic inversion center, the Cu^II^ ion is in a distorted trigonal–bipyramidal coordination geometry formed by two N atoms from a phen ligand, two O atoms from a bridging oxalate ligand and one Cl atom.
μ-Oxalato-1κ2O,O′:2κ2O′′,O′′′-bis(chloro{[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II))
✍ Scribed by Tomyn, Stefaniya V. ;Gumienna-Kontecka, Elźbieta ;Fritsky, Igor O. ;Iskenderov, Turganbay S. ;Światek-Kozłowska, Jolanta
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 235 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
l-Oxalato-1j 2 O,O 0 0 0 :2j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis(chloro{[1-(2pyridyl-jN)ethylidene]hydrazine-jN}copper(II)
📜 SIMILAR VOLUMES
In the title compound, [Cu(C~2~O~4~)(C~6~H~7~NO)~2~]~__n__~, the Cu^II^ atom is six-coordinated in a slightly deformed elongated octahedral arrangement and the 3-(hydroxymethyl)pyridine ligand, surprisingly, acts as a monodentate ligand coordinated only through the N atom of the pyridine ring. The o
l 2 -Oxalato-j 2 O,O 0 0 0 :j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis[aqua(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)] dinitrate dihydrate
1jN,
)(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)]
Bis[l 2 -bis(salicylidene)propane-1,3-diaminatoj 4 O,N,N 0 0 0 ,O 0 0 0 :j 2 O,O 0 0 0 ]bis(l 2 -nitrato-jO:jO 0 0 0 )tricopper(II)