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μ-Oxalato-κ4O,O′:O′′,O′′′-bis[chloro(1,10-phenanthroline-κ2N,N′)copper(II)]

✍ Scribed by Wang, Min ;Hu, Bo ;Deng, Xiao-Tao ;Wang, Cheng-Gang

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 228 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807005806

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✦ Synopsis

In the title dimeric complex, [Cu~2~(C~2~O~4~)Cl~2~(C~12~H~8~N~2~)~2~], which lies on a crystallographic inversion center, the Cu^II^ ion is in a distorted trigonal–bipyramidal coordination geometry formed by two N atoms from a phen ligand, two O atoms from a bridging oxalate ligand and one Cl atom. In the crystal structure, pairs of molecules related by π–π stacking interactions are stacked along the c-axis direction

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✦ Synopsis

μ-Oxalato-κ4O,O′:O′′,O′′′-bis[chloro(1,10-phenanthroline-κ2N,N′)copper(II)]