The title ternary mixed-ligand chromium(III) complex, [Cr(C~5~H~7~O~2~)(C~2~O~4~)(C~12~H~8~N~2~)]·3H~2~O, features a distorted octahedral geometry completed by three different bidentate chelating ligands, __viz__. 1,10-phenanthroline, acetylacetonate and oxalate. Complex molecules are linked by π–π
(Oxalato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)palladium(II) monohydrate
✍ Scribed by Odoko, Mamiko ;Wang, Yue ;Okabe, Nobuo
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 228 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.005 A Ê R factor = 0.025 wR factor = 0.073 Data-to-parameter ratio = 14.4
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
l 2 -Oxalato-j 2 O,O 0 0 0 :j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis[aqua(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)] dinitrate dihydrate
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.004 A Ê R factor = 0.043 wR factor = 0.125 Data-to-parameter ratio = 14.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Zn(C 7 H 3 NO 4 )(C 12 H 8 N 2 )(H 2 O)]ÁH 2 O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO 3 N 3 octa