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Aqua­(oxalato-κ2O,O′)­oxo(1,10-phenanthroline-κ2N,N′)­vanadium(IV)

✍ Scribed by Fu, Yun-Long ;Ren, Jia-Lin ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
232 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.004 A Ê R factor = 0.043 wR factor = 0.125 Data-to-parameter ratio = 14.4

For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


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The title compound, [Zn(C 7 H 3 NO 4 )(C 12 H 8 N 2 )(H 2 O)]ÁH 2 O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO 3 N 3 octa