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Aqua(4-formylbenzoato-κO)(nitrato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)

✍ Scribed by Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
534 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Cu(C~8~H~5~O~3~)(NO~3~)(C~12~H~8~N~2~)(H~2~O)], the Cu^II^ atom adopts a distorted square-pyramidal coordination geometry with an O atom of the nitrate group occupying the apex of the pyramid. The complex molecules are linked into ribbons along the a axis via hydrogen bonding between the water molecule and the nitro anion. π–π stacking interactions between the 4-formylbenzoate and phenanthroline ligands assemble two ribbons into a larger one-dimensional structure. The centroid-to-centroid distances between the overlapping six-membered rings are 3.634 (3) and 3.722 (3) Å.

📜 SIMILAR VOLUMES

Aquabis(4-formylbenzoato)-κ2O,O′;κO-(1,1
Aquabis(4-formylbenzoato)-κ2O,O′;κO-(1,10-phenanthroline-κ2N,N′)cadmium(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 683 KB

The Cd^II^ atom in the title complex, [Cd(C~8~H~5~O~3~)~2~(C~12~H~8~N~2~)(H~2~O)], is coordinated by three O atoms of two formylbenzoate ligands, two N atoms of a 1,10-phenanthroline ligand and one water molecule, giving rise to a trigonal–prismatic coordination geometry. Adjacent complex molecules

Aqua­bis(4-formyl­benzoato-κO)(1,10-phen
Aqua­bis(4-formyl­benzoato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 253 KB

Single-crystal X-ray study T = 295 K Mean (C-C) = 0.003 A R factor = 0.033 wR factor = 0.088 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.