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Aquabis(4-formylbenzoato)-κ2O,O′;κO-(1,10-phenanthroline-κ2N,N′)cadmium(II)

✍ Scribed by Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
683 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The Cd^II^ atom in the title complex, [Cd(C~8~H~5~O~3~)~2~(C~12~H~8~N~2~)(H~2~O)], is coordinated by three O atoms of two formylbenzoate ligands, two N atoms of a 1,10-phenanthroline ligand and one water molecule, giving rise to a trigonal–prismatic coordination geometry. Adjacent complex molecules are linked into a two-dimensional layer structure via hydrogen-bonding interactions.

📜 SIMILAR VOLUMES

Aqua­bis(4-formyl­benzoato-κO)(1,10-phen
Aqua­bis(4-formyl­benzoato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 253 KB

Single-crystal X-ray study T = 295 K Mean (C-C) = 0.003 A R factor = 0.033 wR factor = 0.088 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis(4-formyl­benzoato-κ2O,O′)(1,10-phena
Bis(4-formyl­benzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium(II)–bis­(μ2-4-formyl­benzoato-κ2O:O′)­bis­[(4-formyl­benzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium(II)] (1/1)
✍ Deng, Zhao-Peng ;Gao, Shan ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 307 KB

Bis(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10-phenanthrolinej 2 N,N 0 0 0 )cadmium(II)-bis(l 2 -4-formylbenzoatoj 2 O:O 0 0 0 )bis[(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10phenanthroline-j 2 N,N 0 0 0 )cadmium(II)] (1/1

Aqua(4-formylbenzoato-κO)(nitrato-κO)(1,
Aqua(4-formylbenzoato-κO)(nitrato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 534 KB

In the title complex, [Cu(C~8~H~5~O~3~)(NO~3~)(C~12~H~8~N~2~)(H~2~O)], the Cu^II^ atom adopts a distorted square-pyramidal coordination geometry with an O atom of the nitrate group occupying the apex of the pyramid. The complex molecules are linked into ribbons along the __a__ axis __via__ hydrogen

Aqua(2,2′-bipyridine-κ2N,N′)bis(4-formyl
Aqua(2,2′-bipyridine-κ2N,N′)bis(4-formylbenzoato-κ2O,O′)cadmium(II) monohydrate
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 807 KB

In the mononuclear title compound, [Cd(C~8~H~5~O~3~)~2~(C~10~H~8~N~2~)(H~2~O)]·H~2~O, the Cd atom is __O__,__O__′-chelated by two 4-formylbenzoate monoanions and __N__,__N__′-chelated by 2,2′-bipyridine. It is also coordinated by a water molecule in a monocapped trigonal-prismatic geometry. The coor